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Normalizing Annealing Tool Steels Table Chart
Engineering Materials
Applications & Design
Normalizing and Annealing Temperatures of Tool Steels Table Chart. Annealing is the steady heating of a metal at a certain temperature above the recrystallization phase followed by a gradual cooling process. Normalizing heat treating will create a material that is softer but will not produce the uniform material properties of annealing.. A material can be normalized by heating it to a specific temperature and then letting the material cool to room temperature outside of the oven. This treatment refines the grain size and improves the uniformity of microstructure and properties of hot rolled steel.
Steel
|
Normalizing treatment
temperature (a) |
Annealing (b)
|
||||||||
Temperature
|
Rate of
cooling max |
Hardness
|
||||||||
Type
|
°C
|
|
°F
|
°C
|
°F
|
°C /h
|
°F /h
|
HB
|
||
Molybdenum high-speed steels
|
||||||||||
M1, M10
|
Do not normalize
|
815-970
|
1500-1600
|
22
|
40
|
207-235
|
||||
M2
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
212-241
|
||||
M3, M4
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
223-255
|
||||
M6
|
Do not normalize
|
870
|
1600
|
22
|
40
|
248-277
|
||||
M7
|
Do not normalize
|
815-870
|
1500-1600
|
22
|
40
|
217-255
|
||||
M30, M33, M34,
M36, M41, M42, M46, M47 |
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
235-269
|
||||
M43
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
248-269
|
||||
M44
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
248-293
|
||||
Tungsten hot work steels | ||||||||||
T1
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
217-255
|
||||
T2
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
223-255
|
||||
T4
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
229-269
|
||||
T5
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
235-277
|
||||
T6
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
248-293
|
||||
T8
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
229-255
|
||||
T15
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
241-277
|
||||
Chromium hot work steels | ||||||||||
H10, H11,
H12, H13 |
Do not normalize
|
845-900
|
1550-1650
|
22
|
40
|
192-229
|
||||
H14
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
207-235
|
||||
H19
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
207-241
|
||||
Tungsten hot work steels
|
||||||||||
H21, H22, H25
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
207-235
|
||||
H23
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
212-255
|
||||
H24, H26
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
217-241
|
||||
Molybdenum hot work steels | ||||||||||
H41, H43
|
Do not normalize
|
815-870
|
1500-1600
|
22
|
40
|
207-235
|
||||
H42
|
Do not normalize
|
845-900
|
1550-1650
|
22
|
40
|
207-235
|
||||
High-carbon high chromium cold work steels | ||||||||||
D2, D3, D4
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
217-255
|
||||
D5
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
223-255
|
||||
D7
|
Do not normalize
|
870-900
|
1600-1650
|
22
|
40
|
235-262
|
||||
Medium-alloy air-hardening cold work steels | ||||||||||
A2
|
Do not normalize
|
845-870
|
1550-1600
|
22
|
40
|
201-229
|
||||
A3
|
Do not normalize
|
845-870
|
1550-1600
|
22
|
40
|
207-229
|
||||
A4
|
Do not normalize
|
740-760
|
1360-1400
|
14
|
25
|
200-241
|
||||
A6
|
Do not normalize
|
730-745
|
1350-1375
|
14
|
25
|
217-248
|
||||
A7
|
Do not normalize
|
870-900
|
1600-1650
|
14
|
25
|
235-262
|
||||
A8
|
Do not normalize
|
845-870
|
1550-1600
|
22
|
40
|
192-223
|
||||
A9
|
Do not normalize
|
845-870
|
1550-1600
|
14
|
25
|
212-248
|
||||
A10
|
790
|
1450
|
765-795
|
1410-1460
|
8
|
15
|
235-269
|
|||
Oil-hardening cold work steels
|
||||||||||
O1
|
870
|
1600
|
760-790
|
1400-1450
|
22
|
40
|
183-212
|
|||
O2
|
845
|
1550
|
745-775
|
1375-1425
|
22
|
40
|
183-212
|
|||
O6
|
870
|
1600
|
765-790
|
1410-1450
|
11
|
20
|
183-217
|
|||
O7
|
900
|
1650
|
790-815
|
1450-1500
|
22
|
40
|
192-217
|
|||
Shock-resisting steels
|
||||||||||
S1
|
Do not normalize
|
790-815
|
1450-1500
|
22
|
40
|
183-229(c)
|
||||
S2
|
Do not normalize
|
760-790
|
1400-1450
|
22
|
40
|
192-217
|
||||
S5
|
Do not normalize
|
775-800
|
1425-1475
|
14
|
25
|
192-229
|
||||
S7
|
Do not normalize
|
815-845
|
1500-1550
|
14
|
25
|
187-223
|
||||
Mold steels
|
||||||||||
P2
|
Not required
|
730
|
1350-1500
|
22
|
40
|
103-123
|
||||
P3
|
Not required
|
815
|
1350-1500
|
22
|
40
|
109-137
|
||||
P4
|
Do not normalize
|
870-900
|
1600-1650
|
14
|
25
|
116-128
|
||||
P5
|
Not required
|
845-870
|
1550-1600
|
22
|
40
|
105-116
|
||||
P6
|
Not required
|
845
|
1550
|
8
|
15
|
183-217
|
||||
P20
|
900
|
1650
|
760-790
|
1400-1450
|
22
|
40
|
149-179
|
|||
P21
|
900
|
1650
|
Do not anneal
|
|||||||
Low-alloy special-purpose steels
|
||||||||||
L2
|
870-900
|
16001650
|
760-790
|
1400-1450
|
22
|
40
|
163-197
|
|||
L3
|
900
|
1650
|
790-815
|
1450-1500
|
22
|
40
|
174-201
|
|||
L6
|
870
|
1600
|
760-790
|
1400-1450
|
22
|
40
|
183-212
|
|||
Carbon-tungsten special-purpose steels
|
||||||||||
F1
|
900
|
1650
|
760-800
|
1400-1475
|
22
|
40
|
183-207
|
|||
F2
|
900
|
1650
|
790-815
|
1450-1500
|
22
|
40
|
207-235
|
|||
Water-hardening steels
|
||||||||||
W1, W2
|
790-925(d)
|
1450-1700(d)
|
740-790(e)
|
1360-1450(e)
|
22
|
40
|
156-201
|
|||
W5
|
870-925
|
16001700
|
760-790
|
1400-1450
|
22
|
40
|
163-201
|
(a) Time held at temperature varies from 15 min for small sections to 1 h for large sizes. Cooling is done in still air. Normalizing should not be confused with low-temperature annealing.
(b) The upper limit of ranges should be used for large sections and the lower limit for smaller sections. Time held at temperature varies from 1 h for light sections to 4 h for heavy sections and large furnace charges of high alloy steel.
(c) For 0.25 Si type 183 to 207 HB; for 1.00 Si type, 207 to 229 HB.
(d) Temperature varies with carbon content: 0.60 to 0.75ºC, 815ºC (1500°F); 0.75 to 0.90 ºC, 790ºC (1450ºF); 0.90 to 1.10ºC, 870ºC (1600ºF); 1.10 to 1.40 ºC, 870 to 925ºF (1600 to 1700ºF).
(e) Temperature varies with carbon content: 0.60 to 0.90 ºC, 740 to 790ºC (1360 to 1450ºF); 0.90 to 1.40 ºC, 760 to 790ºC (1400 to 1450ºF).
Source: ASM Handbook Vol. 4, page 715, table 2.
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